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Overspray is caused by the mist that is created when spray painting a surface. The tiny paint particles are light enough to float around in the air, when they land they slowly start to harden and become overspray. Overspray can be removed safely in many cases.
When a part is spraypainted, a mist of paint can float down onto other surfaces. This can happen when a part of a car is being painted. This mist falls down onto other parts and dries up. This is called overspray and shows up as very small specks on top of the paintwork.